Synthesis and Isolation of an Anionic Bis(dipyrido-annulated) N-Heterocyclic Carbene CCC-Pincer Iridium(III) Complex by Facile C–H Bond Activation

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  • Kazuki Nakanishi
    Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan
  • J. Oscar. C. Jimenez-Halla
    Department of Chemistry, Division of Natural and Exact Sciences, University of Guanajuato, Campus Gto, Noria Alta s/n, 36050 Guanajuato, Mexico
  • Seiji Yamazoe
    Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan
  • Masaaki Nakamoto
    Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan
  • Rong Shang
    Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan
  • Yohsuke Yamamoto
    Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan

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Description

Meridional tridentate N-heterocyclic carbene (NHC)-based pincer ligands contribute to a substantial growth in modern organometallic chemistry in both homogeneous catalysis and luminescence materials. Among all NHC-based pincer ligands, the dianionic LX

Journal

  • Inorganic Chemistry

    Inorganic Chemistry 60 (13), 9970-9976, 2021-06-22

    American Chemical Society (ACS)

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