Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics

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Description

<p>A much improved route to 1,1′-bis(arylethynyl)ferrocenes comprising <italic>accessible</italic> thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF–BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.</p>

Journal

  • Dalton Trans.

    Dalton Trans. 43 (41), 15287-15290, 2014

    Royal Society of Chemistry (RSC)

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