DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization
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- R. Aleyda Garza‐Sanchez
- Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster Corrensstrasse 40 48149 Münster Germany
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- Tuhin Patra
- Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster Corrensstrasse 40 48149 Münster Germany
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- Adrian Tlahuext‐Aca
- Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster Corrensstrasse 40 48149 Münster Germany
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- Felix Strieth‐Kalthoff
- Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster Corrensstrasse 40 48149 Münster Germany
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- Frank Glorius
- Organisch-Chemisches Institut Westfälische Wilhelms-Universität Münster Corrensstrasse 40 48149 Münster Germany
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説明
<jats:title>Abstract</jats:title><jats:p>Herein, we report a novel strategy for the activation of DMSO to act as a versatile alkylating agent in heteroarene C−H functionalization. This direct, simple, and mild switch between methylation/trideuteromethylation and methylthiomethylation of heteroarenes was achieved under reagent‐controlled photoredox catalysis conditions. The proposed mechanism is supported by both experimental and computational studies.</jats:p>
収録刊行物
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- Chemistry – A European Journal
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Chemistry – A European Journal 24 (40), 10064-10068, 2018-06-12
Wiley