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Atomistic study on simultaneous achievement of partial crystallization and rejuvenated glassy structure in thermal process of metallic glasses
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- Masato Wakeda
- Research Center for Structural Materials, National Institute for Materials Science, Tsukuba, Japan
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- Junji Saida
- Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai, Japan
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- Tetsu Ichitsubo
- Institute for Materials Research, Tohoku University, Sendai, Japan
Description
The relaxation state and partial crystallization are crucial factors that affect the material properties of metallic glasses. Rejuvenation induces a less relaxed glass state and hence facilitates the control of the relaxation state. The rejuvenation and crystallization during thermal processing are associated closely with the phase changes of metallic glasses upon heating. Most nanocrystalline metallic glasses formed via conventional thermal annealing have a relaxed glassy matrix. In this molecular dynamics study, we investigate the feasibility of thermal processing to simultaneously realise both partial crystallization and rejuvenation using model alloy system. Dynamic mechanical analyses reveal relaxation behaviours and local deformation features of metallic glasses composed of a crystalline phase and a rejuvenated glass matrix. The crystalline phase increases the macroscopic shear stiffness of the composite model over a wide temperature range, whereas it does not significantly affect the internal friction of the rejuvenated glass matrix. In addition, dispersed nanocrystals suppress the development of sharp and concentrated shear localisation in the rejuvenated glass matrix. The simultaneous adjustment of the relaxation state and crystalline phase in the glass matrix is discussed from a viewpoint of the microstructure design of metallic glasses.
Journal
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- Philosophical Magazine
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Philosophical Magazine 102 (13), 1209-1230, 2022-03-09
Informa UK Limited
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Details 詳細情報について
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- CRID
- 1360576196075740288
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- ISSN
- 14786443
- 14786435
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE