Enantioselective C–H Functionalization Using High-Valent Group 9 Metal Catalysts

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  • Tatsuhiko Yoshino
    Faculty of Pharmaceutical Sciences, Hokkaido University, Kita-12 Nishi-6, Kita-ku, Sapporo, Hokkaido 060-0812 , Japan

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<jats:title>Abstract</jats:title> <jats:p>Group 9 transition metals with a cyclopentadienyl-type ligand are highly reactive catalysts for directed C–H functionalization reactions. In this review, we summarize our recent work on the development of enantioselective C–H functionalization reactions using achiral Rh(III) or Co(III) catalysts in combination with an external chiral source such as chiral sulfonates, a Lewis base, or carboxylic acids.</jats:p>

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