Truxenone Triimide: Two‐Dimensional Molecular Arrangements of Triangular Molecules for Air Stable n‐Type Semiconductors

  • Sharvan Kumar
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Yun Hee Koo
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Tomohiro Higashino
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Wakana Matsuda
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Samrat Ghosh
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Yusuke Tsutsui
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Masayuki Suda
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Hiroshi Imahori
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Katsuaki Suzuki
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Hironori Kaji
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
  • Shu Seki
    Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan

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<jats:title>Abstract</jats:title><jats:p>The preparation of a new class of electron deficient organic compounds is of great interest for the development of high‐performance n‐type organic semiconductors. Herein, the facile synthetic protocol for the isolation of the first examples of truxenone triimide (TTI) is reported. The electrochemical analysis of the resulting TTIs confirms that the multi‐imidization helps in lowering the LUMO energy level, tailoring prerequisite optoelectronic and/or semiconducting properties. Their microscopic charge carrier transport properties and dynamics are screened by flash‐photolysis time‐resolved microwave conductivity measurements. Compound <jats:bold>2D</jats:bold> exhibited an electron mobility of 0.27 cm<jats:sup>2</jats:sup> V<jats:sup>−1</jats:sup> s<jats:sup>−1</jats:sup> under ambient conditions.</jats:p>

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