Truxenone Triimide: Two‐Dimensional Molecular Arrangements of Triangular Molecules for Air Stable n‐Type Semiconductors
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- Sharvan Kumar
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Yun Hee Koo
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Tomohiro Higashino
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Wakana Matsuda
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Samrat Ghosh
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Yusuke Tsutsui
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Masayuki Suda
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Hiroshi Imahori
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Katsuaki Suzuki
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Hironori Kaji
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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- Shu Seki
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo‐ku Kyoto 615–8510 Japan
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説明
<jats:title>Abstract</jats:title><jats:p>The preparation of a new class of electron deficient organic compounds is of great interest for the development of high‐performance n‐type organic semiconductors. Herein, the facile synthetic protocol for the isolation of the first examples of truxenone triimide (TTI) is reported. The electrochemical analysis of the resulting TTIs confirms that the multi‐imidization helps in lowering the LUMO energy level, tailoring prerequisite optoelectronic and/or semiconducting properties. Their microscopic charge carrier transport properties and dynamics are screened by flash‐photolysis time‐resolved microwave conductivity measurements. Compound <jats:bold>2D</jats:bold> exhibited an electron mobility of 0.27 cm<jats:sup>2</jats:sup> V<jats:sup>−1</jats:sup> s<jats:sup>−1</jats:sup> under ambient conditions.</jats:p>
収録刊行物
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- Advanced Electronic Materials
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Advanced Electronic Materials 8 (7), 2022-02-23
Wiley
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詳細情報 詳細情報について
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- CRID
- 1360579814643978624
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- ISSN
- 2199160X
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN
- OpenAIRE