Enhancement of lithium-mediated ammonia synthesis by addition of oxygen

  • Katja Li
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Suzanne Z. Andersen
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Michael J. Statt
    SUNCAT Center for Interface Science and Catalysis, Department of Chemical Engineering, Stanford University, Stanford, CA, USA.
  • Mattia Saccoccio
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Vanessa J. Bukas
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Kevin Krempl
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Rokas Sažinas
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Jakob B. Pedersen
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Vahid Shadravan
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Yuanyuan Zhou
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Debasish Chakraborty
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Jakob Kibsgaard
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Peter C. K. Vesborg
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Jens K. Nørskov
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.
  • Ib Chorkendorff
    Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark.

説明

<jats:title>Boosting ammonia with a little oxygen</jats:title> <jats:p> Ammonia synthesis from nitrogen for fertilizer production is highly energy intensive. Chemists are therefore exploring electrochemical approaches that could draw power from renewable sources while generating less waste. One promising cycle involves the reduction of lithium ions at an electrode, with the resultant metal in turn reducing nitrogen and regenerating the ions. Li <jats:italic>et al</jats:italic> . report the counterintuitive result that small quantities of oxygen could enhance the efficiency of this process, which they attribute to diffusional effects that limit excessive lithium reduction. —JSY </jats:p>

収録刊行物

  • Science

    Science 374 (6575), 1593-1597, 2021-12-24

    American Association for the Advancement of Science (AAAS)

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