Nanoscale interfacial engineering enables highly stable and efficient perovskite photovoltaics

  • Anurag Krishna
    Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Hong Zhang
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Zhiwen Zhou
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Thibaut Gallet
    Scanning Probe Microscopy Laboratory, Department of Physics and Materials Science, University of Luxembourg, Luxembourg
  • Mathias Dankl
    Laboratory of Computational Chemistry and Biochemistry, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Olivier Ouellette
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Felix T. Eickemeyer
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Fan Fu
    Laboratory for Thin Films and Photovoltaics, Empa-Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland
  • Sandy Sanchez
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Mounir Mensi
    Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Valais Wallis, CH-1951 Sion, Switzerland
  • Shaik M. Zakeeruddin
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Ursula Rothlisberger
    Laboratory of Computational Chemistry and Biochemistry, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • G. N. Manjunatha Reddy
    Univ. Lille, CNRS, Centrale Lille Institut, Univ. Artois, UMR 8181-UCCS-Unité de Catalyse et Chimie du Solide, F-59000 Lille, France
  • Alex Redinger
    Scanning Probe Microscopy Laboratory, Department of Physics and Materials Science, University of Luxembourg, Luxembourg
  • Michael Grätzel
    Laboratory of Photonics and Interfaces, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland
  • Anders Hagfeldt
    Laboratory of Photomolecular Science, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, Lausanne 1015, Switzerland

書誌事項

公開日
2021
権利情報
  • http://creativecommons.org/licenses/by-nc/3.0/
DOI
  • 10.1039/d1ee02454j
公開者
Royal Society of Chemistry (RSC)

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説明

<jats:p>The molecular level interface engineering with a multifunctional ligand 2,5-thiophenedicarboxylic acid suppresses interfacial ion diffusion and inhibits I<jats:sub>2</jats:sub> formation, which leads to high operational stability with <jats:italic>T</jats:italic><jats:sub>80</jats:sub> of 3570 h along with PCE of 23.4%.</jats:p>

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