Mechanochemistry: New Tools to Navigate the Uncharted Territory of “Impossible” Reactions
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- Federico Cuccu
- Dipartimento di Scienze Chimiche e Geologiche Università degli Studi di Cagliari Cittadella Universitaria 09042 Monserrato, Cagliari Italy
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- Lidia De Luca
- Dipartimento di Chimica e Farmacia Università degli Studi di Sassari via Vienna 2 07100 Sassari Italy
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- Francesco Delogu
- Dipartimento di Ingegneria Meccanica, Chimica e dei Materiali Università degli Studi di Cagliari Via Marengo 2 09123 Cagliari Italy
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- Evelina Colacino
- ICGM Univ Montpellier, CNRS, ENSCM Montpellier France
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- Niclas Solin
- Department of Physics Chemistry and Biology (IFM) Electronic and Photonic Materials (EFM) Building Fysikhuset, Room M319, Campus Valla Sweden
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- Rita Mocci
- Dipartimento di Scienze Chimiche e Geologiche Università degli Studi di Cagliari Cittadella Universitaria 09042 Monserrato, Cagliari Italy
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- Andrea Porcheddu
- Dipartimento di Scienze Chimiche e Geologiche Università degli Studi di Cagliari Cittadella Universitaria 09042 Monserrato, Cagliari Italy
抄録
<jats:title>Abstract</jats:title><jats:p>Mechanochemical transformations have made chemists enter unknown territories, forcing a different chemistry perspective. While questioning or revisiting familiar concepts belonging to solution chemistry, mechanochemistry has broken new ground, especially in the panorama of organic synthesis. Not only does it foster new “thinking outside the box”, but it also has opened new reaction paths, allowing to overcome the weaknesses of traditional chemistry exactly where the use of well‐established solution‐based methodologies rules out progress. In this Review, the reader is introduced to an intriguing research subject not yet fully explored and waiting for improved understanding. Indeed, the study is mainly focused on organic transformations that, although impossible in solution, become possible under mechanochemical processing conditions, simultaneously entailing innovation and expanding the chemical space.</jats:p>
収録刊行物
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- ChemSusChem
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ChemSusChem 15 (17), e202200362-, 2022-07-21
Wiley