Synthetic Molecular Photoelectrochemistry: New Frontiers in Synthetic Applications, Mechanistic Insights and Scalability
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- Shangze Wu
- Universität Regensburg Fakultät für Chemie und Pharmazie 93040 Regensburg Germany
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- Jaspreet Kaur
- Universität Regensburg Fakultät für Chemie und Pharmazie 93040 Regensburg Germany
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- Tobias A. Karl
- Universität Regensburg Fakultät für Chemie und Pharmazie 93040 Regensburg Germany
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- Xianhai Tian
- Universität Regensburg Fakultät für Chemie und Pharmazie 93040 Regensburg Germany
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- Joshua P. Barham
- Universität Regensburg Fakultät für Chemie und Pharmazie 93040 Regensburg Germany
説明
<jats:title>Abstract</jats:title><jats:p>Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for the generation and handling of reactive intermediates. PEC permits selective single‐electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. Herein, the most recent contributions are reviewed, demonstrating exciting new opportunities, namely, the combination of PEC with other reactivity paradigms (hydrogen‐atom transfer, radical polar crossover, energy transfer sensitization), scalability up to multigram scale, novel selectivities in SET super‐oxidations/reductions and the importance of precomplexation to temporally enable excited radical ion catalysis.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 61 (12), e202107811-, 2022-02-09
Wiley