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Palladium-Catalyzed Unimolecular Fragment Coupling of N-Allylamides Bearing a Tethered Nucleophile with the Translocation of an Amide Group
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- Mamoru Tobisu
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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- Ryoma Shimazumi
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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- Takuya Kodama
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
Bibliographic Information
- Published
- 2023-01-30
- Resource Type
- journal article
- DOI
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- 10.1055/a-2022-1905
- Publisher
- Georg Thieme Verlag KG
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Description
<jats:title>Abstract</jats:title> <jats:p>The palladium-catalyzed reaction of N-allylamides bearing a tethered nucleophile results in the extrusion of an amide moiety in the form of an isocyanate, with its subsequent capture by the pendant nucleophile. This reaction involves the net catalytic transposition of an amide group.</jats:p>
Journal
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- Synthesis
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Synthesis 56 (01), 134-142, 2023-01-30
Georg Thieme Verlag KG
Related Data
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Details 詳細情報について
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- CRID
- 1360581942657957504
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- ISSN
- 1437210X
- 00397881
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE
