A long-lived charge-separated state of spiro compact electron donor–acceptor dyads based on rhodamine and naphthalenediimide chromophores

DOI Web Site 1 Citations
  • Xiao Xiao
    State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China
  • Ivan Kurganskii
    International Tomography Center, SB RAS Institutskaya Str., 3A, and Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia
  • Partha Maity
    Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
  • Jianzhang Zhao
    State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China
  • Xiao Jiang
    Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, P. R. China
  • Omar F. Mohammed
    Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
  • Matvey Fedin
    International Tomography Center, SB RAS Institutskaya Str., 3A, and Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia

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Description

<jats:p>Spiro compact rhodamine-naphthalenediimide electron donor–acceptor dyads show a long-lived charge separated state (lifetime: 0.72 μs) based on the electron spin control effect were reported.</jats:p>

Journal

  • Chemical Science

    Chemical Science 13 (45), 13426-13441, 2022

    Royal Society of Chemistry (RSC)

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