Cuprophilic interactions in highly luminescent dicopper(<scp>i</scp>)–NHC–picolyl complexes – fast phosphorescence or TADF?

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<p>Cuprophilic interactions can greatly enhance the radiative rate constants <italic>via</italic> either exceptionally fast phosphorescence or TADF, and thus present a design motif for highly efficient CuI-based emitters.</p>

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