Controlled Positioning of Activated Ester Moieties on Well‐Defined Linear Polymer Chains
説明
<jats:title>Abstract</jats:title><jats:p>The successful sequence‐controlled installation of an activated ester using a newly designed monomer pentafluorophenyl 4‐maleimidobenzoate is demonstrated. Pentafluorophenyl 4‐maleimidobenzoate is kinetically installed at different stages of a nitroxide‐mediated polymerization, namely, near the α‐chain end and in the middle of a PS chain. In addition, successful installation of apolar and polar functional groups is achieved via post‐polymerization functionalization, which demonstrated the versatility of the synthesis of a universal precursor for locally functionalized polymers.</jats:p>
収録刊行物
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- Macromolecular Rapid Communications
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Macromolecular Rapid Communications 33 (1), 54-60, 2011-11-25
Wiley
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詳細情報 詳細情報について
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- CRID
- 1360846639543004032
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- ISSN
- 15213927
- 10221336
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- データソース種別
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- Crossref
- KAKEN