Spectral splitting photovoltaics using perovskite and wideband dye-sensitized solar cells

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<jats:title>Abstract</jats:title><jats:p>The extension of the light absorption of photovoltaics into the near-infrared region is important to increase the energy conversion efficiency. Although the progress of the lead halide perovskite solar cells is remarkable, and high conversion efficiency of >20% has been reached, their absorption limit on the long-wavelength side is ∼800 nm. To further enhance the conversion efficiency of perovskite-based photovoltaics, a hybridized system with near-infrared photovoltaics is a useful approach. Here we report a panchromatic sensitizer, coded DX3, that exhibits a broad response into the near-infrared, up to ∼1100 nm, and a photocurrent density exceeding 30 mA cm<jats:sup>−2</jats:sup> in simulated air mass 1.5 standard solar radiation. Using the DX3-based dye-sensitized solar cell in conjunction with a perovskite cell that harvests visible light, the hybridized mesoscopic photovoltaics achieved a conversion efficiency of 21.5% using a system of spectral splitting.</jats:p>

収録刊行物

  • Nature Communications

    Nature Communications 6 (1), 8834-, 2015-11-05

    Springer Science and Business Media LLC

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