Catalytic Transformation of Cyclohexene Hydroperoxides to Epoxy Alcohols with Vanadyl Acetylacetonate

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  • Takashi Itoh
    Department of Chemical Engineering, Faculty of Engineering Science, Osaka University
  • Kiyotomi Kaneda
    Department of Chemical Engineering, Faculty of Engineering Science, Osaka University
  • Shiichiro Teranishi
    Department of Chemical Engineering, Faculty of Engineering Science, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Cyclohexene hydroperoxide and its methyl derivatives undergo rearrangement in the presence of the vanadyl acetylacetonate catalyst to the corresponding epoxyalcohols with high cis-stereoselectivity in high yields.</jats:p>

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