Reaction of a Thioaminyl Diradical with 7,7,8,8-Tetracyanoquinodimethane (TCNQ). The Formation of a Cyclophane Compound
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- Yozo Miura
- Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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- Tsuguyori Ohana
- Department of Applied Chemistry, Faculty of Engineering, Osaka City University
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- Teruo Kunishi
- Department of Applied Chemistry, Faculty of Engineering, Osaka City University
抄録
<jats:title>Abstract</jats:title> <jats:p>The reactions of thioaminyl mono- (MONOR) and diradicals (DIR) with 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been investigated. The reactions of TCNQ with MONOR gave 1:2 adducts of TCNQ and MONOR in 85–88% yields, while the reaction with DIR afforded either a cyclophane compound (77%), or an alternating polymer of TCNQ and DIR (59 wt%), dependent on the structures of DIR.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 63 (1), 269-271, 1990-01-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644033528704
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- NII論文ID
- 130001980175
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- ISSN
- 13480634
- 00092673
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- データソース種別
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