Crystal Structure and Physical Properties of (BDT-TTP)2ClO4

DOI PDF 24 Citations 5 References
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Tokyo Institute of TechnologyO-okayama, Meguro-ku, Tokyo 152
  • Yohji Misaki
    Division of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto 606-01
  • Hideki Fujiwara
    Division of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto 606-01
  • Tokio Yamabe
    Division of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto 606-01

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<jats:title>Abstract</jats:title> <jats:p>The ClO4, BF4, and ReO4 salts of BDT-TTP, 2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene, are isostructural, having uniform columns of the donor molecules. These salts are essentially metallic down to low temperatures, though the resistivity increases to some extent below 200 K. The thermoelectric power and ESR show simple metal-like behavior down to low temperatures.</jats:p>

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