Organic Metal with a High Oxidation State (+5/3), (TTM–TTP)(I3)5/3

DOI DOI PDF 9 Citations 5 References
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Tokyo Institute of TechnologyO-okayama, Tokyo 152
  • Yohji Misaki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto 606-01
  • Tokio Yamabe
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto UniversityYoshida, Kyoto 606-01

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<jats:title>Abstract</jats:title> <jats:p>The crystal structure of the title compound, where TTM–TTP is 2,5-bis [4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalene, has been determined by X-ray analysis. The donors form a uniform stack, which is responsible for metallic conduction down to TMI = 20 K. The anions are composed of discrete I3− and an infinite chain of I3−. Each donor has anomalously large positive charge of +5/3.</jats:p>

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