Supersonic Jet Spectroscopic Study of 1-Methyl-2(1<i>H</i>)-pyridinimine and Its Deuterated Analog

DOI PDF 被引用文献1件 参考文献14件
  • Mark A Young
    Department of Chemistry, University of IowaIowa City, Iowa 52242, U.S.A
  • Gary DeBoer
    Department of Chemistry, University of IowaIowa City, Iowa 52242, U.S.A
  • Akira Fujimoto
    Department of Materials Science and Engineering, Tokyo Denki UniversityKanda, Chiyoda-ku, Tokyo 101
  • Naoya Iwasaki
    Department of Materials Science and Engineering, Tokyo Denki UniversityKanda, Chiyoda-ku, Tokyo 101
  • Hassime Traore
    Department of Chemistry, University of Wisconsin-WhitewaterWhitewater, Wisconsin 53190, U.S.A
  • Ivan Yourshaw
    Department of Chemistry, University of California-BerkeleyCalifornia 94720, U.S.A

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<jats:title>Abstract</jats:title> <jats:p>The laser-induced fluorescence spectra and the fluorescence lifetimes of 1-methyl-2(1H)-pyridinimine and its deuterated analog were measured in a supersonic jet. The spectral results reveal a number of low frequency modes which are assigned to torsional motions involving the methyl group. The two major groups of peaks observed are ascribed to the presence of cis/trans conformers in the supersonic expansion.</jats:p>

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