Synthesis, Crystal Structure, and Some Spectrochemical Properties of Optically Active <i>S</i>-Bridged Trinuclear Complex <i>ΔΔ</i>-[Ni{Co(aet)2(<i>R</i>-pn)}2]4+ (aet = 2-Aminoethanethiolate, <i>R</i>–pn = (<i>R</i>)–1,2-Propanediamine)
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- Yasunori Yamada
- Department of Chemistry, University of Tsukuba Tsukuba, Ibaraki 305-8571
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- Yoko Maeda
- Department of Chemistry, University of Tsukuba Tsukuba, Ibaraki 305-8571
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- Yoshitaro Miyashita
- Department of Chemistry, University of Tsukuba Tsukuba, Ibaraki 305-8571
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- Kiyoshi Fujisawa
- Department of Chemistry, University of Tsukuba Tsukuba, Ibaraki 305-8571
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- Takumi Konno
- Department of Chemistry, Faculty of Engineering, Gunma University Kiryu, Gunma 376-8516
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- Ken-ich Okamoto
- Department of Chemistry, University of Tsukuba Tsukuba, Ibaraki 305-8571
説明
<jats:title>Abstract</jats:title> <jats:p>The reaction of cis-[CoCl2(R-pn)2]+ (R–pn = (R)–1,2-propanediamine) with [Ni(aet)2] (aet = 2–aminoethanethiolate) in water stereoselectively gave an S-bridged trinuclear complex, [Ni{Co(aet)2(R-pn)}2]4+, accompanied by the ligand-transfer of aet from Ni2+ to Co3+. The ΔΔ isomer of the trinuclear complex was selectively formed. The spectrochemical properties of theΔΔ isomer are also discussed in relation to the stereochemical behavior.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 73 (5), 1219-1220, 2000-05-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644034780160
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- NII論文ID
- 130004150639
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- ISSN
- 13480634
- 00092673
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- データソース種別
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