Single-component Magnetic Molecular Conductor [Fe(dmdt)2] (dmdt: dimethyltetrathiafulvalenedithiolate)

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  • Biao Zhou
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Satomi Ogura
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Noriko Kato
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Yuki Idobata
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Akiko Kobayashi
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Hayao Kobayashi
    Department of Chemistry, College of Humanities and Sciences, Nihon University

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<jats:title>Abstract</jats:title> <jats:p>Molecular metal complexes with interactions between localized spins and conduction electrons are expected to show interesting electronic and magnetic properties. We prepared magnetic molecular conductors of iron complexes with extended TTF ligands and investigated their crystal structures and electronic and magnetic properties, from which we concluded that the single-component molecular iron complex has the dimeric form of [Fe(dmdt)2].</jats:p>

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  • Chemistry Letters

    Chemistry Letters 42 (9), 977-979, 2013-06-01

    Oxford University Press (OUP)

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