Cyclic TTF Tetramer Linked by Methylenedithio Spacers

DOI PDF 2 Citations 18 References
  • Ken-ichi Nakamura
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Yuuki Okada
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Takashi Shirahata
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

Description

<jats:title>Abstract</jats:title> <jats:p>A new cyclic tetrathiafulvalene (TTF) tetramer 1 was synthesized. The cyclic voltammogram of 1 consists of four pairs of two-electron redox waves. UV–vis–NIR spectra of the oxidative species of 1 suggest that 12+, 14+, and 16+ possibly adopt two pairs of dimeric TTF structures that interact with each other through the so-called side-by-side interaction.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 43 (5), 708-710, 2014-02-07

    Oxford University Press (OUP)

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