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Intramolecular Oligomerization of Disilalkylene {-Me2Si(CH2)nSiMe2-} Bridged Cyclic Triacetylenes
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- Keisuke Ebata
- NTT Basic Research Laboratories
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- Tsukasa Matsuo
- Department of Chemistry, Faculty of Science, Tohoku University
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- Tsuyotoshi Inoue
- Department of Chemistry, Faculty of Science, Tohoku University
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- Yuko Otsuka
- Department of Chemistry, Faculty of Science, Tohoku University
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- Chizuko Kabuto
- Department of Chemistry, Faculty of Science, Tohoku University
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- Akira Sekiguchi
- Department of Chemistry, Faculty of Science, Tohoku University
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- Hideki Sakurai
- Department of Industrial Chemistry, Faculty of Science, Science University of Tokyo
Description
<jats:title>Abstract</jats:title> <jats:p>Disilalkylene bridged cyclic triacetylenes are prepared and subjected to the transition metal complex mediated reactions. In particular, the reaction with (methylcyclopentadienyl)tricarbonylmanganese gave a variety of π-electron systems such as fulvene, dimethylenecyclobutene, and biallene. Structures and reactions of these π-electron systems are described.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 25 (12), 1053-1054, 1996-12-01
Oxford University Press (OUP)
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Details 詳細情報について
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- CRID
- 1360846644039275776
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- NII Article ID
- 130004420106
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- OpenAIRE
