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Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8<i>π</i> Allyl Anion System
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- Akira Sekiguchi
- Department of Chemistry, University of Tsukuba
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- Tsukasa Matsuo
- Department of Chemistry, University of Tsukuba
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- Keisuke Ebata
- NTT Basic Research Laboratories
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- Hideki Sakurai
- Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
Description
<jats:title>Abstract</jats:title> <jats:p>Reduction of persilylated dimethylenecyclobutene with lithium metal in 1,2-dimethoxyethane yields green crystals of persilylated dimethylenecyclobutene dianion dilithium as the first 6C-8π allyl anion system. The molecular structure, determined by X-ray crystallography, is discussed in comparison to that of the neutral starting molecule.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 25 (12), 1133-1134, 1996-12-01
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360846644039286528
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- NII Article ID
- 130004420105
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- ISSN
- 13480715
- 03667022
- http://id.crossref.org/issn/03667022
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- Data Source
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- Crossref
- CiNii Articles
- OpenAIRE
