Structure and Properties of (DTM-TTP)(TCNQ)(TCE) and the Related Complex

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  • Takehiko Mori
    Department of Organic and Polymeric Materials, Tokyo Institute of Technology
  • Kyoji Murata
    Department of Organic and Polymeric Materials, Tokyo Institute of Technology
  • Yohji Misaki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Kazuyoshi Tanaka
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University

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<jats:title>Abstract</jats:title> <jats:p>DTM-TTP (2-(4,5-bisthiomethyl-1,3-dithiol-2-ylidene)-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene) and TCNQ (tetracyanoquinodimethane) form the title 1:1 complex including 1,1,2-trichloroethane (TCE). The crystal structure is composed of segregated stacks. This complex undergoes a metal-insulator transition around 100 K. Thermoelectric power takes small positive values, and the magnetic susceptibility is paramagnetic down to low temperatures.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 27 (5), 435-436, 1998-05-01

    Oxford University Press (OUP)

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