Photon-, Reductant-, and Oxidant-Induced Substitution of a CO Ligand on closo-[Cp*2Fe3S2(CO)3] (Cp* = η5-C5Me5)

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  • Masahiro Yuki
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Toshiaki Mitsui
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Shinji Inomata
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Masaaki Okazaki
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Hiroshi Ogino
    Department of Chemistry, Graduate School of Science, Tohoku University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Substitution of CO in closo-[Cp*2Fe3S2(CO)3] (1) by PPh3 was accelerated upon photolysis or by treatment with reductant or oxidant to give mono(PPh3)-substituted clusters. In the redoxinduced reaction, [1]− and [1]+ were proposed as labile intermediates to substitution of CO.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 27 (6), 561-562, 1998-06-01

    Oxford University Press (OUP)

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