Cyano-bridged One-dimensional SmIII–FeIII Molecule-based Magnet with an Ordering Temperature of 3.4 K
-
- Chunhua Ge
- Department of Chemistry, Tsinghua University
-
- Hui-Zhong Kou
- Department of Chemistry, Tsinghua University
-
- Zhong-Hai Ni
- Department of Chemistry, Tsinghua University
-
- Yun-Bo Jiang
- Department of Chemistry, Tsinghua University
-
- Li-Fang Zhang
- Department of Chemistry, Tsinghua University
-
- Ai-Li Cui
- Department of Chemistry, Tsinghua University
-
- Osamu Sato
- Institute for Materials Chemistry and Engineering, Kyushu University
説明
<jats:title>Abstract</jats:title> <jats:p>A new cynao-bridged SmIII–FeIII bimetallic coordination polymer has been prepared by the reaction of (n-Bu4N)3Fe(CN)6 and Sm(NO3)3·6H2O in a DMF–H2O media. The complex consists of alternate Sm(DMF)4(H2O)2 and Fe(CN)6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with Tc = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.</jats:p>
収録刊行物
-
- Chemistry Letters
-
Chemistry Letters 34 (9), 1280-1281, 2005-08-13
Oxford University Press (OUP)
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1360846644040709504
-
- NII論文ID
- 130004722726
-
- ISSN
- 13480715
- 03667022
-
- データソース種別
-
- Crossref
- CiNii Articles