A Key Role of Orbital Interaction in the Main Group Element-containing π-Electron Systems

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  • Shigehiro Yamaguchi
    Department of Chemistry, Graduate School of Science, Nagoya University, and PRESTO, Japan Science and Technology Agency (JST)
  • Kohei Tamao
    International Research Center for Elements Science, Institute for Chemical Research, Kyoto University

Bibliographic Information

Published
2004-11-27
Rights Information
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.2005.2
Publisher
Oxford University Press (OUP)

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Description

<jats:title>Abstract</jats:title> <jats:p>Various types of main group element-containing π-electron systems have been synthesized using silole, dibenzoborole, or bis-silicon-bridged stilbene as the key building units. In these π-electron systems, the orbital interaction between the main group element moiety and the π-conjugated framework, such as pπ–π* and σ*–π* conjugation, plays a crucial role in determining their characteristic electronic structures and makes them promising materials for applications in organic electronics and optoelectronics.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 34 (1), 2-7, 2004-11-27

    Oxford University Press (OUP)

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