Novel Bis-fused π-Electron Donor Composed of Tetrathiafulvalene and Tetraselenafulvalene

  • Minoru Ashizawa
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Ken-ichi Ishidzu
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Masaki Watanabe
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Tetsuhiko Tanahashi
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Takashi Shirahata
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Tadashi Kawamoto
    Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

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説明

<jats:title>Abstract</jats:title> <jats:p>A new donor (ST-STP), in which tetrathiafulvalene and tetraselenafulvalene are fused, has been synthesized. This donor shows unexpectedly large on-site Coulomb repulsion compared with other bis-fused TTF systems. In (ST-STP)ReO4, intramolecular charge disproportionation is suggested by the crystal structure and transport properties.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 39 (10), 1093-1095, 2010-09-11

    Oxford University Press (OUP)

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