How to Construct Chiral Macrocycles from Anthracene Units and Acetylene Linkers

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  • Shinji Toyota
    Department of Chemistry, Faculty of Science, Okayama University of Science

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<jats:title>Abstract</jats:title> <jats:p>We propose strategies to construct chiral macrocycles by modification of the fundamental compound, 1,8-anthrylene–ethynylene cyclic tetramer, which features a diamond-prism structure. The incorporation of other anthracene units or diacetylene linkers produces structures of various symmetries. The enantiomers of some chiral derivatives could be resolved by chiral HPLC. The structures, dynamic behavior, and chiroptical properties of these macrocycles are summarized.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 40 (1), 12-18, 2010-11-25

    Oxford University Press (OUP)

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