New Molecular Metals Based on a Tetrathiapentalene Donor with Peripheral Methoxy Groups

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  • Tetsuya Ito
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Ken-ichi Nakamura
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Takashi Shirahata
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Tadashi Kawamoto
    Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

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<jats:title>Abstract</jats:title> <jats:p>A new tetrathiapentalene (TTP) donor 2-(4,5-dimethoxy-1,3-dithiol-2-ylidene)-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene (DMO-TTP) has been synthesized, and the PF6 and AsF6 salts have also been prepared by electrochemical crystallization. X-ray structure analyses have revealed that intermolecular and intramolecular CH···O hydrogen bondings are constructed in the neutral crystal and the cation radical salts, respectively. The PF6 and AsF6 salts have a so-called β-type arrangement of the donors and show metallic behavior down to around 10 K.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 40 (1), 81-83, 2010-12-16

    Oxford University Press (OUP)

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