Thioamides and Thioformamides for Sequential Reactions with Organolithium and Grignard Reagents

DOI DOI PDF 被引用文献39件 参考文献177件 オープンアクセス
  • Toshiaki Murai
    Department of Chemistry, Faculty of Engineering, Gifu University
  • Yuichiro Mutoh
    Department of Chemistry, Faculty of Engineering, Gifu University

書誌事項

公開日
2011-12-24
資源種別
journal article
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.2012.2
  • 10.1002/chin.201222193
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>Sequential reactions of thioamides and thioformamides with organolithium and Grignard reagents are described. Thioiminium salts derived from these sulfur isologues of amides readily react with lithium acetylides to lead to several types of products, including α,β-unsaturated ketones, whereas sequential additions of lithium acetylides and Grignard reagents afford propargylamines. The direct addition of organolithium and Grignard reagents to thioformamides proceeds with high efficiency to give a range of tertiary amines.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 41 (1), 2-8, 2011-12-24

    Oxford University Press (OUP)

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