Network Formation and Mechanical Properties of Telechelic Associating Polymers with Fixed Junction Multiplicity

DOI Web Site Web Site 被引用文献1件 参考文献42件
  • Hiroto Ozaki
    Department of Polymer Chemistry Graduate School of Engineering Kyoto University Katsura Kyoto 615‐8510 Japan
  • Tsuyoshi Koga
    Department of Polymer Chemistry Graduate School of Engineering Kyoto University Katsura Kyoto 615‐8510 Japan

この論文をさがす

説明

<jats:p>A statistical–mechanical theory of thermoreversible gelation which is formed by monodisperse telechelic associating polymers with junction multiplicity of three is developed. In the present theory, the effect of loop formation is considered. Using the theory, the properties of the system are obtained, such as the state of association of polymers, the sol–gel transition line, and the number concentration of elastically effective chains. In addition, a Monte Carlo simulation of a bead‐spring model of monodisperse telechelic associating polymers is performed. The simulation results are in good agreement with the present theoretical results. Furthermore, the shear modulus is calculated by an application of phantom network theory and compared with the experimental data. The theoretical results agree well with the experimental results. It is shown that the loop formation occurs especially in dilute regime and causes the decrease of the modulus in the regime. <jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/mats201600076-abs-0001-m.png"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (42)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ