Vanadium pentacyanonitrosylmolybdate-based magnet exhibiting a high magnetic ordering temperature of 200 K

DOI Web Site Web Site 1 Citations 67 References

Search this article

Description

Abstract Vanadium pentacyanonitrosylmolybdate, K0.82V1.06[Mo(CN)5(NO)]·3.8H2O, is synthesized from K4[Mo(CN)5(NO)]·2H2O and VCl3 under an argon atmosphere. X-ray powder diffraction and extended X-ray absorption fine structure measurements show that the crystal structure is face-centered cubic (fcc) with a lattice constant of 10.410(8) A, where V and Mo ions are in octahedral coordination geometries. This compound shows ferrimagnetism with a high Curie temperature of 200 K, in which the magnetic spins on VII (S = 3/2) and VIII (S = 1) antiparallely align with the spins on MoI (S = 1/2).

Journal

Citations (1)*help

See more

References(67)*help

See more

Related Projects

See more

Keywords

Report a problem

Back to top