Decarbonylative Methylation of Aromatic Esters by a Nickel Catalyst
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- Toshimasa Okita
- Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555, Japan
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- Kei Muto
- Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555, Japan
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- Junichiro Yamaguchi
- Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555, Japan
書誌事項
- 公開日
- 2018-05-08
- 資源種別
- journal article
- DOI
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- 10.1021/acs.orglett.8b01233
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
A Ni-catalyzed decarbonylative methylation of aromatic esters was achieved using methylaluminums as methylating agents. Dimethylaluminum chlorides uniquely worked as the methyl source. Because of the Lewis acidity of aluminum reagents, less reactive alkyl esters could also undergo the present methylation. By controlling the Lewis acidity of aluminum reagents, a chemoselective decarbonylative cross-coupling between alkyl esters and phenyl esters was successful.
収録刊行物
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- Organic Letters
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Organic Letters 20 (10), 3132-3135, 2018-05-08
American Chemical Society (ACS)
