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Molecular Alloy with Diluted Magnetic Moments—Molecular Kondo System
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- Yuki Idobata
- Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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- Biao Zhou
- Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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- Akiko Kobayashi
- Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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- Hayao Kobayashi
- Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan
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Description
[Ni(1-x)Cu(x)(tmdt)(2)] (tmdt = trimethylenetetrathiafulvalenedithiolate) was prepared for realizing molecular Kondo systems. Magnetic moments (S = (1)/(2)) are considered to exist at the central {CuS(4)} parts of Cu(tmdt)(2) molecules. The χT-versus-T curve of the system with x ≈ 0.15 showed a broad peak at ~10 K. The decrease in the χT value below 10 K is consistent with a singlet ground state, as expected for a Kondo system. However, in the system with x ≈ 0.27, the χT value decreased when the temperature was lowered to 2 K, indicating antiferromagnetic interactions between magnetic moments through π-d interactions. Although the susceptibility anomaly suggested that the π-d interactions become important at T20 K, the observed resistivity (ρ(obs)) showed no resistivity minimum characteristic of a Kondo system down to 4.2 K. However, the differential resistivity Δρ(T) = ρ(obs) - ρ(L)(T) showed a logarithmic resistivity increase at 8-20 K with decreasing temperature, where ρ(L)(T) is a fitted function of ρ(obs) obtained at T50 K that is considered to represent approximately the temperature dependence of the resistivity without spin scattering of the conduction electrons.
Journal
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 134 (2), 871-874, 2011-12-23
American Chemical Society (ACS)
