- 【Updated on May 12, 2025】 Integration of CiNii Dissertations and CiNii Books into CiNii Research
- Trial version of CiNii Research Knowledge Graph Search feature is available on CiNii Labs
- Suspension and deletion of data provided by Nikkei BP
- Regarding the recording of “Research Data” and “Evidence Data”
Dimeric and Trimeric Tetrathiafulvalenes with Strong Intramolecular Interactions in the Oxidized States
-
- Ken-ichi Nakamura
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Tsuyoshi Takashima
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Takashi Shirahata
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Shojun Hino
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Masashi Hasegawa
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Yasuhiro Mazaki
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
-
- Yohji Misaki
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan, and Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato. Minami-ku, Sagamihara, Kanagawa 252-0373, Japan
Search this article
Description
New dimeric and trimeric TTF derivatives with methylenedithio spacers (1a,b, 2a, and 2b) have been synthesized. X-ray structure analysis revealed that TTF units of the dimer 1b adopted distorted face-to-face overlapping arrangement both in intra- and intermolecular stacking. Cyclic voltammetric study indicated that trimeric 2a was in favor of taking di- and tetracationic states, while the dimeric 1a was in favor of taking a monocation. The absorption spectroscopic study suggested an existence of the strong face-to-face interaction particularly in di-, tri-, and tetracationic state of the trimeric TTF derivatives.
Journal
-
- Organic Letters
-
Organic Letters 13 (12), 3122-3125, 2011-05-18
American Chemical Society (ACS)
