Desymmetrization of<i>meso</i>-Aziridines with TMSNCS Using Metal Salts of Novel Chiral Imidazoline–Phosphoric Acid Catalysts
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- Shuichi Nakamura
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Mutsuyo Ohara
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Madoka Koyari
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Masashi Hayashi
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Kengo Hyodo
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Nadaf Rashid Nabisaheb
- Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
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- Yasuhiro Funahashi
- Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan
Description
<jats:title>Abstract</jats:title><jats:p>Good enantioselectivities are achieved using a novel BINOL‐type catalyst for the reactions of aziridines with isothiocyanate (II) or thiobenzoic acid.</jats:p>
Journal
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- Organic Letters
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Organic Letters 16 (17), 4452-4455, 2014-08-08
American Chemical Society (ACS)