Single crystal cis–trans photoisomerizations of 2-(9-anthrylmethylene)-1-indanones

書誌事項

公開日
2009
資源種別
journal article
DOI
  • 10.1039/b821900a
公開者
Royal Society of Chemistry (RSC)

説明

cis–transPhotoisomerizations of 2-(9-anthrylmethylene)-1-indanones were carried out in the solid state. The photoisomerizations proceeded without destruction of the crystal lattices. The crystal structural changes accompanying the photoisomerizations were observed by X-ray diffraction analysis. From the structural correlation between the reactants and products, the single-crystal isomerizations were proved to proceed through one bond flip (OBF), where the indanonyl moiety of the molecule rotates around the isomerizing double bond.

収録刊行物

  • CrystEngComm

    CrystEngComm 11 (7), 1235-, 2009

    Royal Society of Chemistry (RSC)

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