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Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes
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- Tasuku Inami
- Department of Material Chemistry
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- Takuya Kurahashi
- Department of Material Chemistry
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- Seijiro Matsubara
- Department of Material Chemistry
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Description
<p>The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the <italic>syn</italic>-adducts exclusively.</p>
Journal
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- Chemical Communications
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Chemical Communications 51 (7), 1285-1288, 2015
Royal Society of Chemistry (RSC)
