Nickel-catalyzed borylation of arenes and indoles via C–H bond cleavage
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- Takayuki Furukawa
- Department of Applied Chemistry
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- Mamoru Tobisu
- Department of Applied Chemistry
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- Naoto Chatani
- Department of Applied Chemistry
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説明
<p>The first nickel-catalyzed method for the borylation of carbon–hydrogen bonds in arenes and indoles is described. The use of an N-heterocyclic carbene ligand is essential for an efficient reaction, with an <italic>N</italic>-cyclohexyl-substituted derivative being optimal. This method is readily applied to the gram scale synthesis of 2-borylindole.</p>
収録刊行物
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- Chemical Communications
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Chemical Communications 51 (30), 6508-6511, 2015
Royal Society of Chemistry (RSC)