Bromine-Radical-Mediated Site-Selective Allylation of C(sp3)–H Bonds

DOI PDF 被引用文献4件
  • Mitsuhiro Ueda
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Ayami Maeda
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Kanako Hamaoka
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Mika Sasano
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Takahide Fukuyama
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Ilhyong Ryu
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University

書誌事項

公開日
2019-01-07
資源種別
journal article
権利情報
  • https://creativecommons.org/licenses/by-nd-nc/4.0/
DOI
  • 10.1055/s-0037-1610413
公開者
Georg Thieme Verlag KG

この論文をさがす

説明

<jats:p>The C(sp3)–H allylation of alkanes is investigated by using allyl bromides under radical reaction conditions. In many cases, methine C–H allylation preceded methylene and methyl C–H allylation with complete or a high degree of site selectivity. The C–H allylation of allylic compounds, such as allylbenzene, gives 1,5-dienes with the SH2′ reactions of the allyl radicals occurring at the less hindered carbon.</jats:p>

収録刊行物

  • Synthesis

    Synthesis 51 (05), 1171-1177, 2019-01-07

    Georg Thieme Verlag KG

被引用文献 (4)*注記

もっと見る

関連プロジェクト

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ