Thiolate-based One-dimensional Flexible Pb–MOFs Exhibiting a Large Sorption Hysteresis Phenomenon

  • Yoshinobu Kamakura
    Department of Chemistry, Graduate School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • Ryo Hamano
    Department of Chemistry, Graduate School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • Yuiga Nakamura
    Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
  • Kunihisa Sugimoto
    Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
  • Hirofumi Yoshikawa
    Department of Nanotechnology for Sustainable Energy, Graduate School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
  • Daisuke Tanaka
    Department of Chemistry, Graduate School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan

Description

A novel thiolate-based Pb-metal-organic framework, [Pb2(Hdtd)4·2DMSO]n (KGF-2·DMSO, H2dtd = 6-dibutylamino-1,3,5-triazine-2,4-dithol and DMSO = dimethyl sulfoxide) was prepared. The crystal structu...

Journal

  • Chemistry Letters

    Chemistry Letters 50 (5), 1053-1056, 2021-05-05

    Oxford University Press (OUP)

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