Artificial co-enzyme based on carbamoyl-modified viologen derivative cation radical for formate dehydrogenase in the catalytic CO<sub>2</sub> reduction to formate

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<p>The interaction between the single-electron reduced carbamoyl-modified-4,4-bipyridinium salt and CbFDH in the CO2 reduction to formate is elucidated by enzymatic kinetic analysis, the docking simulation and density functional theory calculation.</p>

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