X-ray absorption and X-ray photoelectron spectroscopic studies of air-oxidized chromium nitride thin films

書誌事項

公開日
1996-08
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/s0040-6090(96)88640-8
公開者
Elsevier BV

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説明

Abstract The surface oxidation of CrN thin films prepared by the cathode are ion plating method was studied by X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) using soft X-rays from synchrotron radiation. The results indicate that molecular nitrogen is formed in the interstitial position of the chromium oxide matrix at the initial stage of oxidation. On further oxidation, at a higher temperature, molecular nitrogen is gradually released from the surface, with part of the displaced nitrogen remaining in the interstitial position.

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