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- Changho Yoo
- Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro, Yuseong-gu Daejeon 34141 Republic of Korea
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- Yunho Lee
- Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) 291 Daehak-ro, Yuseong-gu Daejeon 34141 Republic of Korea
説明
<jats:title>Abstract</jats:title><jats:p>A T‐shaped Ni<jats:sup>I</jats:sup> complex was synthesized using a rigid acridane‐based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half‐filled <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/anie201704487-math-0001.png" xlink:title="urn:x-wiley:14337851:media:anie201704487:anie201704487-math-0001" /> orbital, this three‐coordinate Ni<jats:sup>I</jats:sup> species reveals unique open‐shell reactivity including the homolytic cleavage of various σ‐bonds, such as H−H, N−N, and C−C.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 56 (32), 9502-9506, 2017-06-07
Wiley