Fabrication of asymmetrically superhydrophobic cotton fabrics via mist copolymerization of 2,2,2‐trifluoroethyl methacrylate

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  • GuangHui Xi
    Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Materials and Textile, Zhejiang Sci‐Tech University, Xiasha Higher Education Zone Hangzhou 310018 People's Republic of China
  • WanChao Fan
    Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Materials and Textile, Zhejiang Sci‐Tech University, Xiasha Higher Education Zone Hangzhou 310018 People's Republic of China
  • Lu Wang
    Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Materials and Textile, Zhejiang Sci‐Tech University, Xiasha Higher Education Zone Hangzhou 310018 People's Republic of China
  • XiangDong Liu
    Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, College of Materials and Textile, Zhejiang Sci‐Tech University, Xiasha Higher Education Zone Hangzhou 310018 People's Republic of China
  • Takeshi Endo
    Molecular Engineering Institute, Kinki University Kayanomori Iizuka 820‐8555 Japan

説明

<jats:title>ABSTRACT</jats:title><jats:p>We report here a simple strategy for fabricating asymmetrically superhydrophobic cotton fabric via a mist copolymerization of three monomers, 2,2,2‐trifluoroethyl methacrylate (TFMA), 2‐isocyanatoethyl methacrylate (IEM), and divinylbenzene (DVB). The copolymer layer on the cotton surface was confirmed by X‐ray photoelectron spectroscopy (XPS) analysis and attenuated total reflection (ATR) accessory, and the nanoscale hierarchical structures in the polymeric layer were demonstrated by observation of field emission scanning electron microscope (FE‐SEM). Surface characterization reveals that the modified surface is superhydrophobic, but the opposite side of the modified cotton fabric has the hydrophilic nature of cotton. More experimental data suggest that the good water adsorptivity and vapor transmissibility of the original cotton fabric were inherited after the surface modification. These properties are of great significance in textile and medical applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. <jats:bold>2015</jats:bold>, <jats:italic>53</jats:italic>, 1862–1871</jats:p>

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