Chemically Induced Dynamic Nuclear Polarization XI. Intermediary vinyl alcohol during photochemical reactions of acetaldehyde and of acetoin

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<jats:title>Abstract</jats:title><jats:p>Vinylalcohol, formed by disproportionation of α‐hydroxyethyl radicals, is detected by NMR. spectroscopy during photoreactions of acetaldehyde and acetoin in solution and slowly tautomerizes to acetaldehyde.</jats:p>

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