Fe-doped La0.5Sr0.5TiO3−δ nanoparticles: A diluted magnetic oxide system

  • Santi Maensiri
    Khon Kaen University Integrated Nanotechnology Research Center (INRC) and Small and Strong Materials Group (SSMG), Department of Physics, Faculty of Science, , Khon Kaen 40002, Thailand
  • Kwanruthai Wongsaprom
    Khon Kaen University Integrated Nanotechnology Research Center (INRC) and Small and Strong Materials Group (SSMG), Department of Physics, Faculty of Science, , Khon Kaen 40002, Thailand
  • Ekaphan Swatsitang
    Khon Kaen University Integrated Nanotechnology Research Center (INRC) and Small and Strong Materials Group (SSMG), Department of Physics, Faculty of Science, , Khon Kaen 40002, Thailand
  • Supapan Seraphin
    The University of Arizona Department of Materials Science and Engineering, , Tucson, Arizona 85721, USA

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<jats:p>We report room-temperature ferromagnetism in ∼11.4–14.6nm nanoparticles of La0.5Sr0.5Ti0.985Fe0.015O3−δ. Nanoparticles of undoped and Fe-doped samples were synthesized by a polymerized complex method and were characterized using x-ray diffraction, transmission electron microscopy, and vibrating-sample magnetometer. The undoped samples exhibit a diamagnetic behavior, whereas the Fe-doped samples are ferromagnetic having the specific magnetizations of 0.041–0.101emu∕g at 10kOe. Our results indicate that the ferromagnetic property of La0.5Sr0.5Ti0.985Fe0.015O3−δ system is intrinsic and is not a result of any secondary magnetic phase or cluster formation. The finding of room-temperature ferromagnetism in this system would stimulate further interest in the area of diluted magnetic oxides.</jats:p>

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